Formation of soil macropores and preferential migration of linear alkylbenz- ene sulfonate (LAS) in soils

Effects of freeze-thaw and wet-dry cycles on the formation of soil macropores and preferential flow under simulative conditions in the laboratory, and preferential migration of linear alkylbenzene sulfonate (LAS) in paddy and soybean soils in field lysimeters were studied. Results showed that both freeze-thaw and wet-dry cycles could cause macropores and preferential flow in soils and that the former was stronger than the latter. The preferential breakthrough of LAS through 1.5 m soil monolith was 23 days for both paddy and soybean soils. However, their leachate volumes at preferential breakthrough were much different, i.e. 69 mm for paddy soil and only 9 mm for soybean soil. The leachate volumes at equilibrium governed by soil adsorption/desorption processes were very similar for soils cropped to paddy rice (185 mm) and soybean (178 mm) though their breakthrough times were much different, i.e. 44 days for the former and 58 days for the latter. The preferential breakthrough of LAS was 21 and 35 days ahead of equilibrium breakthrough for paddy and soybean soils, respectively. The peak LAS concentrations resulted from preferential breakthrough accounted for 20-30% of those at equilibrium in soybean soil. This ratio was as high as 30-86% in paddy soil. Preferential migration of LAS could not be observed in repacked soil monolith without macropores.